Considerable effort has been expended in order to understand the mechanism of manganese catalases and to develop functional mimics for these enzymes. For many years, the most efficient reactivity ...

Photodisproportionation of a bis-corrole−diiron(IV)−μ-oxo dimer gave a corrole−iron(III) species and a corrole−iron(V)−oxo species that can be detected and studied in real time. Air oxidation of the ...