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As Mission Control eventually knew it would, the CO2 level reached 7.5mmHg at 80:30 GET, triggering a master alarm, a level set pre-flight to advise the crew to change the LiOH canister.
As Apollo 13 approached earth, the winds stopped and the storm shifted direction. ... "My alarm systems had worked, but they had not come on quickly enough to save their lives," he said.